Has anyone started using this yet? It's the new Front Page, but I haven't heard much about it. I downloaded the 60 day trial, and it seems to be okay so far, but I don't have much in the way of web design experience.

i am using it. before that i used to work in dreamweaver but after i got my hand on expression web, i simply started to ignore dreamweaver. expression web is simply amazing. i designed my whole site using expression web. its great...!!!!

Expression Web is solid. Have you checked out the video tutorials?
What used to take me 2 weeks now takes me 3 days. Make sure you know how to create a dynamic web template and use it to generate all the other pages in your site.

If you're a college student, you can probably download it for free, not a trial. It's a special promotion by MS to get students to use it instead of Dreamweaver, which is the dominant and pricey alternative.